You can change pH by adding acid (lower) or by adding KH (higher). Tannins and HCl are both examples of adding acids. so Ph goes lower. Alkalinity will be reduced, because you lowered pH by adding acid and it consumed some KH.There's some anecdotal evidence of people using HCl to reduce Kh (and in turn, pH), but nothing too official.
pH is also reduced through Tannins, which I don't believe alter the Kh of the water.
None of these things are acting like CO2 though, it does not consume KH by its presence in the water, as other acids do. More here: CO2 and pH: Understanding Henry's Law
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