I think those numbers are about right
Mg is a little high, or to put it differently you dont need that much ime. My tap comes with 30-35 ppm Ca and 4-6 Mg. Its what Ive always used in all the tanks. Ive spent long periods of time running different levels of Mg, all the way up to 20 down to just whats in the tap. And this is with anywhere from 6 to 12 tanks going at the same time, some sand, some soil, different KH, etc
I never noticed anything specifically that adding more helps. And up in the 15-20 range plants seem to have a harder time getting enough K. This would coincide with Mulders chart and Ive seen it happen first hand, repeatable. I cruised at around 10 for a few years by adding an extra 5
About a year and a half ago I stopped adding any extra, just the 4-6 from tap along with the 30-35 Ca. Plant growth across the board has never been better. Not that lower Mg helps anything just the point that more isnt needed. We've all seen the crop studies with the 3:1-2:1 ratios. Thats why I started adding it to begin with 12 years ago like so many other hobbyists
But Ive found more often than not these ideal ratios from crop studies dont always apply to our underwater plants. Fe:Mn is another example. Personally with Mg I would err on the low side because it really doesnt matter and too much can start affecting other nutrients
In your case with 22 ppm Ca Id just go with the 4 thats in your tap. Also you may want to raise Ca into the low 30s. 22 might be enough but quite a few plants will do better with more, Rotala sunset and Florida come to mind, downoi, AR
About your water change dosing question. Youre exactly right and thats why daily dosing, especially macros, is not ideal if youre doing more than say 25-30% water changes. Because like you said its a big drop and takes a long time to catch back up in daily dribbles
Even with 50% I like to dose extra macros right after then a couple smaller doses through the week. Say 50% of the weekly total post wc, then 2x 25% through the week. If youre set on daily with an autodoser Id make a solution (or dry dose) to add about 50% of the weeks total after the water change, then you can daily the rest of it out in equal doses. That'll be a much more consistent water column
This is all just my personal phylosophy based on my own anecdotal experiences and what happens in my tanks. Others may have a different opinion or experiences