Regarding your surface biofilm. I have nothing scientific to back this up,. but when this shows up in one of my tanks, I take water from an existing tank and add it to the biofilm tank. My theory being that the biofilm is just a type of bacteria. That type doesn't exist on my 'good' tank so by adding water from the good tank to the biofilm tank I am introducing a competing bacteria and the biofilm bacteria eventually die out.
Like I said, I have nothing to prove this is real, but it's been working for me. It's also reliant on actually having an established tank that doesn't have biofilm regardless of the use of a skimmer. So there is that.